Anagram & Information om | Engelska ordet CARBONYLS

Exempel på hur man kan använda CARBONYLS i en mening

• Aside from bonds to organyl fragments or molecules, bonds to 'inorganic' carbon, like carbon monoxide (metal carbonyls), cyanide, or carbide, are generally considered to be organometallic as well.
• Other organic carbonyls are urea and the carbamates, the derivatives of acyl chlorides chloroformates and phosgene, carbonate esters, thioesters, lactones, lactams, hydroxamates, and isocyanates.
• The underlying concept has also been applied to π-systems involving heteroatoms, such as carbonyls and imines, which furnish the corresponding heterocycles; this variant is known as the hetero-Diels–Alder reaction.
• Although this term could refer to any organic compound containing two carbonyl groups, it is used more specifically to describe molecules in which both carbonyls are in close enough proximity that their reactivity is changed, such as 1,2-, 1,3-, and 1,4-dicarbonyls.
• He discovered nickel carbonyl, a previously unknown compound and the first-discovered in the class of metal carbonyls, which could be easily decomposed to produce pure nickel from its ores through the Mond process.
• Biogenic volatile organic compounds (BVOCs) encompass VOCs emitted by plants, animals, or microorganisms, and while extremely diverse, are most commonly terpenoids, alcohols, and carbonyls (methane and carbon monoxide are generally not considered).
• This is presumably due to the considerably slower reaction with carbonyls as compared to sulfones and sulfoxides.
• The ligands involved in π backbonding can be broken into three groups: carbonyls and nitrogen analogs, alkenes and alkynes, and phosphines.
• He lectured across the world on metal complexes of cyclopentadienyl, indenyl, arenes, olefins, and metal carbonyls.
• The term DNA glycation applies to DNA damage induced by reactive carbonyls (principally methylglyoxal and glyoxal) that are present in cells as by-products of sugar metabolism.
• For polar solvents, valinomycin will mainly expose the carbonyls to the solvent and in nonpolar solvents the isopropyl groups are located predominantly on the exterior of the molecule.
• Reactions between aldimines and α-methylene carbonyls are also considered Mannich reactions because these imines form between amines and aldehydes.
• Related Lewis acid-promoted reactions include as epoxide ring openings and decomplexation of dienes from iron carbonyls.
• Thiazolidines functionalized with carbonyls at the 2 and 4 positions, the thiazolidinediones, are drugs used in the treatment of diabetes mellitus type 2.
• Oxoammonium cations are isoelectronic with carbonyls and structurally related to aldoximes (hydroxylamines), and aminoxyl (nitroxide) radicals, with which they can interconvert via a series of redox steps.
• DNA damages are induced by reactive carbonyls, principally methylglyoxal and glyoxal, at a frequency similar to that of oxidative DNA damages.
• Metal carbonyls are toxic by skin contact, inhalation or ingestion, in part because of their ability to carbonylate hemoglobin to give carboxyhemoglobin, which prevents the binding of oxygen.
• Acylals are obtained by reaction of carbonyls with acetic anhydride or other acid anhydrides and a suitable catalyst, for instance with sulfated zirconia at low temperatures when used as protective groups for aldehydes.
• Both ruthenium and samarium have shown high yields and high stereoselectivity in the reduction of carbonyls to alcohols.
• It is an cytosolic NADPH-dependent oxidoreductase that catalyzes the reduction of a variety of aldehydes and carbonyls, including monosaccharides, and primarily known for catalyzing the reduction of glucose to sorbitol, the first step in polyol pathway of glucose metabolism.

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