Anagram & Information om | Engelska ordet NHCS

Exempel på hur du använder NHCS i en mening

• The cyclic(alkyl)(amino)carbenes (CAACs) has already been known as both a better donor and better acceptor than n-heterocyclic carbenes (NHCs) due to its higher highest occupied molecular orbital (HOMO) and lower lowest unoccupied molecular orbital (LUMO).
• In chemistry, mesoionic carbenes (MICs) are a type of reactive intermediate that are related to N-heterocyclic carbenes (NHCs); thus, MICs are also referred to as abnormal N-heterocyclic carbenes (aNHCs) or remote N-heterocyclic carbenes (rNHCs).
• His research group explores a wide range of topics including the development and application of N-heterocyclic carbenes (NHCs) in catalysis, exploration and use of NHCs as surface modifyers, C-H activation, asymmetric organocatalysis, chemo- and enantioselective hydrogenation of aromatic compounds, photoredox catalysis and energy transfer photocatalysis, heterogeneous catalysis, Metal Organic Frameworks/MOFs, development and use of lipid analogs, and the development of reaction screening technologies.
• The transmetallated NHCs can either be isolated for subsequent reaction with palladium in a two-step method, or generated in the presence of palladium in a one-pot reaction.
• Arduengo demonstrated that deprotonating these salts produces NHCs that are isolable and relatively stable, provided that the heterocycle nitrogen atoms have appropriate substituents.
• Lavallo and Grubbs rationalize the transformation by emphasizing the capacity of NHCs to catalytically induce the formation of metal-metal bonds, where the steric hinderance of the NHC is essential, in particular, for the lability of the NHC (in coordination and dissociation) in the cycle.

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