Information om | Engelska ordet COORDINATIVELY

Exempel på hur man kan använda COORDINATIVELY i en mening

• Being coordinatively saturated, the hydrate is of little value as a catalyst in Friedel-Crafts alkylation and related reactions.
• In octahedral complexes, reductive elimination can be very slow from the coordinatively saturated center, and often, reductive elimination only proceeds via a dissociative mechanism, where a ligand must initially dissociate to make a five-coordinate complex.
• These special anions are essential components of homogeneous alkene polymerisation catalysts, where the active catalyst is a coordinatively unsaturated, cationic transition metal complex.
• The parent compound ruthenocene is unreactive because it is coordinatively saturated and contains no reactive groups.
• A particularly common subset of sigma complexes are those featuring an agostic interaction where a C–H σ-bond on one of its ligands 'leans' towards and interacts with the coordinatively unsaturated metal center to form a chelate.
• The cavity within the cage-like structure of borospherene, as well as borospherene's coordinatively unsaturated hexagonal and heptagonal faces, allows for the possibility of its endohedral or exohedral doping.

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